13.2.1 Unified Atomic Mass Unit ($u$), Isotopes, Isobars, and Isotones
- Unified Atomic Mass Unit ($u$): Defined as exactly $1/12th$ of the mass of an unbound neutral Carbon-12 ($12C$) atom at rest: $$1 u = 1.992647 × 10-26 kg12 = 1.660539 × 10-27 kg$$ $$1 u \equiv 931.5 MeV/c^2 \quad (E = 931.5 MeV)$$
- Constituents of Nucleus (Nucleons):
- Proton ($p$): Charge $= +e = +1.602 × 10-19 C$, Mass $m_p = 1.00727 u = 1.67262 × 10-27 kg$.
- Neutron ($n$): Discovered by James Chadwick (1932) by bombarding Beryllium with $α$-particles. Neutral ($q=0$), Mass $m_n = 1.00866 u = 1.6749 × 10-27 kg$. Free neutron is unstable ($τ ≈ 1000 s$, decays to $p + e^- + \bar{ν}_e$), but stable inside bound nuclei.
- Nuclide Classification ($^A_ZX$):
- Isotopes: Same atomic number $Z$, different neutron number $N$ and mass number $A$ (e.g. $^1_1H, ^2_1H, ^3_1H$; $3517Cl, 3717Cl$). Same chemical properties.
- Isobars: Same mass number $A$, different $Z$ and $N$ (e.g. $^3_1H$ and $^3_2He$; $4018Ar, 4020Ca$).
- Isotones: Same neutron number $N = A - Z$, different $Z$ and $A$ (e.g. $198\ 80Hg$ and $197\ 79Au$ where $N = 118$).