Home › Physics › Modern Physics › Radioactivity and Nuclear Decay Laws
Modern Physics

Radioactivity and Nuclear Decay Laws

Radioactivity is the spontaneous disintegration of unstable atomic nuclei accompanied by the emission of ionizing radiation such as alpha particles, beta particles, and gamma rays. The process follows a statistical first-order decay law independent of external physical and chemical conditions.

UP TGT ScienceUP PGT PhysicsStudy Notes + Practice

Scope and prerequisites

TGT core

Basic properties of alpha, beta, and gamma rays, radioactive displacement laws, half-life, mean life, and simple radioactive decay law.

PGT extension

Successive transformations, radioactive equilibrium, secular and transient equilibrium, carbon dating, alpha-decay tunneling theory, and neutrino hypothesis in beta decay.

Prerequisites

  • Atomic structure and mass defect
  • Binding energy per nucleon curve
  • Exponential functions and differential equations

Nature and Properties of Radiations

  • Alpha particles are doubly ionized helium nuclei (42He) carrying a charge of +2e and a mass approximately four times that of a proton.
  • Beta particles are high-speed electrons (or positrons) originating from the nucleus via neutron-proton conversion.
  • Gamma rays are high-frequency electromagnetic quanta emitted during transitions between nuclear energy states.

Law of Radioactive Decay

  • The rate of disintegration of radioactive nuclei is directly proportional to the number of undecayed nuclei present at that instant.
  • The decay probability per unit time is a constant characteristic of the radioactive species, known as the decay constant.
  • Radioactive decay is a purely statistical phenomenon; it is impossible to predict the exact moment a specific nucleus will decay.

Half-Life and Mean Life

  • Half-life (T1/2) is the time interval required for the number of active nuclei to reduce to half of its initial value.
  • Mean life (τ) is the sum of the ages of all nuclei divided by the total number of nuclei initially present, representing the reciprocal of the decay constant.
  • Both parameters are independent of temperature, pressure, chemical combination, and initial quantity.

Radioactive Equilibrium

  • In a chain of successive disintegrations (A → B → C), if the half-life of parent A is much greater than that of daughter B, secular equilibrium is established.
  • At secular equilibrium, the activity of the daughter nuclide equals the activity of the parent nuclide.
  • Transient equilibrium occurs when the parent's half-life is longer than the daughter's, but of comparable magnitude.

Derivations

Exponential Decay Law

Conditions: Single radioactive isotope with constant decay constant λ

  • Write the differential rate equation: dN/d$t = -\lambdaN$
  • Separate variables: dN / $N = -\lambda dt$
  • Integrate both sides from N0 at t = 0 to N at time t: ∫ (dN / N) = -λ ∫ dt
  • Obtain ln(N / N0) = -λt

Result: N(t) = N_0 e^{-\lambda t}

Relation between Half-Life and Decay Constant

Conditions: Standard exponential decay model

  • Substitute N = N0 / 2 and t = T1/2 into the decay equation
  • N_0 / $2 = N_0 e^{-\lambda T_{1/2}}$
  • Cancel N0 and take natural logarithm of both sides: ln(2) = λ T1/2
  • Isolate half-life

Result: $T_{1/2} = \frac{\ln 2}{\lambda} \approx \frac{0.693}{\lambda}$

Formula sheet

Formula / lawEquationVariables and unitsConditions
Decay Law Equation$$N(t) = N_0 e^{-\lambda t}$$N(t) = nuclei at time t, $N_0 = initial nuclei$, \lambda = decay constant
dimensionless number, s^{-1}
Constant decay probability per unit time
Half-Life Formula$$T_{1/2} = \frac{0.693}{\lambda}$$$T_{1/2} = half-life$, \lambda = decay constant
s
First-order nuclear kinetics
Mean Life Formula$$\tau = \frac{1}{\lambda} = \frac{T_{1/2}}{0.693}$$\tau = mean life, $T_{1/2} = half-life$
s
Valid for exponential decay
Activity of a Sample$$A(t) = \left|\frac{dN}{dt}\right| = \lambda N = A_0 e^{-\lambda t}$$A(t) = activity, $A_0 = initial activity$
Becquerel (Bq) or Ci
Standard decay
Nuclei Remaining after n Half-Lives$$N = N_0 \left(\frac{1}{2}\right)^n$$$n = number of half-lives elapsed (t / T_{1/2})$
dimensionless
Exact integer or fractional half-lives
Secular Equilibrium Condition$$\lambda_1 N_1 = \lambda_2 N_2$$\lambda_1, $N_1 = parent decay constant$ and number; \lambda_2, $N_2 = daughter parameters$
s^{-1}
T_{1/2, 1} \gg T_{1/2, 2}
Successive Decay General Equation (Bateman Solution for Daughter)$$N_2(t) = \frac{\lambda_1 N_{10}}{\lambda_2 - \lambda_1} \left(e^{-\lambda_1 t} - e^{-\lambda_2 t}\right)$$$N_2(t) = daughter nuclei$, $N_{10} = initial parent nuclei$
dimensionless
N_{2}(0) = 0
Alpha Decay Energy (Q-value)$$Q = (m_p - m_d - m_\alpha) c^2$$$m_p = parent mass$, $m_d = daughter mass$, $m_\alpha = \alpha particle mass$
J or MeV
Conservation of relativistic energy and momentum

Graphs and experiments

Exponential Decay Curve

Draw: A rectangular hyperbola-like decreasing curve of N versus t, showing successive halving of N at equal time intervals T1/2.

Interpret: Demonstrates that the number of radioactive nuclei decreases exponentially with time.

Exam use: Used to graphically determine half-life and decay constant.

Logarithmic Decay Curve

Draw: A straight line plot of ln(N) versus t with a negative slope equal to -λ and y-intercept ln(N0).

Interpret: Linearization of the exponential law allows precise calculation of the decay constant from experimental data.

Exam use: Tested in numerical and conceptual questions regarding slope interpretation.

Geiger-Müller Counter Characteristic Curve

Draw: Count rate versus applied potential difference showing the starting voltage, plateau region, and discharge region.

Interpret: Identifies the working plateau where count rate is independent of voltage fluctuations.

Exam use: Instrumental setup questions in practical-oriented physics examinations.

Solved numericals

TGT core

The half-life of a radioactive substance is 4 days. If the initial mass is 64 g, find the mass remaining after 12 days.

  • Determine the number of half-lives elapsed: $n = t / T_{1/2} = 12 / 4 = 3$
  • Apply the formula: $N = N_0 (1/2)^n$
  • Calculate: Mas$s = 64 * (1/2)^3 = 64 * (1/8) = 8 g$

Answer: 8 g

PGT extension

A radioactive material has a decay constant of 0.05 day-1. Calculate its mean life and the time taken for 75% of the sample to decay.

  • Calculate mean life: $\tau = 1 / \lambda = 1 / 0.05 = 20 days$
  • For 75% decay, the remaining fraction is 25%, i.e., N / $N_0 = 0.25 = (1/2)^2$, meaning 2 half-lives have passed.
  • Alternatively, use $t = -(1 / \lambda) \ln(N / N_0) = -(1 / 0.05) \ln(0.25) = -20 * (-1.386) = 27.72 days$

Answer: Mean life = 20 days, Time taken = 27.72 days

PGT extension

In a radioactive series, nuclide A decays to B with a decay constant λ1 = 0.1 h-1, and B decays to stable C with λ2 = 0.5 h-1. Initially, only A is present with N10 = 1000 nuclei. Find the number of daughter nuclei B at t = 0.

  • Use the general equation for daughter nuclei B: $N_2(t) = [(\lambda_1 N_{10}) / (\lambda_2 - \lambda_1)] [exp(-\lambda_1 t) - exp(-\lambda_2 t)]$
  • Substitute t = 0: exp(0) - exp(0) = 1 - 1 = 0
  • Therefore, at t = 0, the number of daughter nuclei B is zero.

Answer: 0 nuclei

Assumptions and limitations

  • Radioactivity is assumed to be an entirely nuclear property unaffected by external physical conditions such as temperature, pressure, or electric and magnetic fields. However, orbital electron capture decay rates can show extremely minute variations under extreme chemical environments.

Common misconceptions

Common error: Radioactivity rate decreases over time because radioactive atoms 'get old' or fatigue.

Correct: The decay probability of an individual nucleus remains constant over time; the decrease in total activity is due to the decreasing number of remaining undecayed nuclei.

Radioactive decay is a random, memoryless Poisson process.

Common error: Gamma rays carry a net positive or negative electric charge.

Correct: Gamma rays are uncharged electromagnetic photons.

Unlike alpha and beta particles, gamma rays are not deflected by electric or magnetic fields.

Quick revision

  • Decay law: $N = N_0 e^{-\lambda t}$
  • Decay Law Equation: N(t) = N_0 e^{-\lambda t}
  • Half-Life Formula: $T_{1/2} = \frac{0.693}{\lambda}$

Must remember

  • Alpha particles are doubly ionized helium nuclei ($^{4}_{2}\text{He}$) with a charge of $+2e$ and a mass roughly four times that of a proton.
  • Beta particles are high-speed electrons or positrons emitted from the nucleus during neutron-proton conversions.
  • Gamma rays are high-frequency uncharged electromagnetic quanta emitted during transitions between nuclear energy states.
  • The rate of disintegration is directly proportional to the number of undecayed nuclei: $-\frac{dN}{dt} = \lambda N$.
  • Radioactive decay is a purely statistical, memoryless phenomenon governed by first-order kinetics.
  • Half-life ($T_{1/2}$) and mean life ($\tau$) are independent of external physical factors like temperature, pressure, or chemical combination.
  • The relationship between mean life and half-life is $\tau = \frac{1}{\lambda} = \frac{T_{1/2}}{0.693}$.
  • At secular equilibrium in a decay chain, the activity of the daughter nuclide equals the activity of the parent nuclide ($\lambda_1 N_1 = \lambda_2 N_2$).

Glossary

Decay Constant ($lambda$)The probability of decay of a nucleus per unit time.
Half-Life ($T_{1/2}$)The time required for half of the initial radioactive nuclei to decay.
Mean Life ($\tau$)The average lifetime of a radioactive nucleus, equal to the reciprocal of the decay constant.
Secular EquilibriumA state in radioactive decay chains where the parent half-life is vastly greater than the daughter half-life, leading to equal activities.
Activity ($A$)The total number of disintegrations per unit time in a radioactive sample, measured in Becquerels (Bq).

Properties of Radioactive Radiations

RadiationNatureChargePenetrating Power
Alpha ($\alpha$)Helium nucleus ($^{4}_{2}\text{He}$)$+2e$Low (Stopped by paper)
Beta ($\beta$)High-speed electron/positron$-e$ or $+e$Moderate (Stopped by thin aluminum sheet)
Gamma ($\gamma$)Electromagnetic quantumZeroHigh (Requires thick lead sheet)

Practice Quiz

Choose an option to reveal the explanation.

1. What is the nature of an $\alpha$ particle emitted during radioactive decay?

Explanation: $\alpha$ particles are doubly ionized helium nuclei containing two protons and two neutrons, carrying a charge of $+2e$.

2. Which of the following radiations is unaffected by external electric and magnetic fields?

Explanation: $\gamma$ rays are uncharged electromagnetic photons and thus experience no deflection in electric or magnetic fields.

3. The rate of radioactive decay at any instant is proportional to:

Explanation: According to the radioactive decay law, the rate of disintegration $-\frac{dN}{dt}$ is directly proportional to the number of undecayed nuclei $N$ present at that instant.

4. What is the relation between the decay constant $\lambda$ and the half-life $T_{1/2}$?

Explanation: Using $N(t) = N_0 e^{-\lambda t}$ at $t = T_{1/2}$, $N = N_0/2$, which yields $T_{1/2} = \frac{ln 2}{lambda} approx \frac{0.693}{lambda}.

5. The mean life $\tau$ of a radioactive substance is related to its decay constant $\lambda$ as:

Explanation: The mean life $\tau$ is defined as the reciprocal of the decay constant, i.e., $\tau = \frac{1}{\lambda}$.

6. After three half-lives ($n = 3$), the fraction of initial undecayed nuclei remaining is:

Explanation: The remaining fraction is given by $\left(\frac{1}{2}\right)^n = \left(\frac{1}{2}\right)^3 = \frac{1}{8}$.

7. Under what condition is secular equilibrium established in a radioactive series ($A arrow B arrow C$)?

Explanation: Secular equilibrium occurs when $T_{1/2, 1} gg T_{1/2, 2}$, meaning the parent decays so slowly that its quantity remains practically constant over many daughter half-lives.

8. At secular equilibrium between parent ($1$) and daughter ($2$), which relation holds true for their activities ($A_1$ and $A_2$)?

Explanation: At secular equilibrium, $\lambda_1 N_1 = \lambda_2 N_2$, which implies that the activity of the parent equals the activity of the daughter ($A_1 = A_2$).

9. Which physical parameter can alter the half-life of a radioactive sample?

Explanation: Radioactive decay is a nuclear phenomenon and is entirely independent of external physical and chemical conditions such as temperature, pressure, and chemical combination.

10. What is the SI unit of radioactivity (activity)?

Explanation: The SI unit of activity is the Becquerel (Bq), defined as one disintegration per second.

11. In $\beta^-$ decay, the fundamental nuclear process involves:

Explanation: In $\beta^-$ decay, a neutron inside the nucleus converts into a proton, an electron ($\beta^-$), and an electron antineutrino.

12. The Q-value of an $\alpha$ decay process is given by:

Explanation: The Q-value represents the energy released, calculated from the mass defect between the parent mass ($m_p$) and the sum of daughter ($m_d$) and $\alpha$ particle ($m_alpha$) masses multiplied by $c^2$.

13. Transient equilibrium occurs when the parent's half-life is:

Explanation: Transient equilibrium takes place when the parent's half-life is longer than the daughter's, but both are of comparable magnitude.

14. Why is radioactive decay considered a statistical phenomenon?

Explanation: Radioactivity is governed by probability laws; while the macroscopic decay rate is predictable, individual nuclear decay is random and memoryless.

15. If a radioactive nuclide has a decay constant $\lambda = 0.0693\text{ day}^{-1}$, what is its half-life?

Explanation: $T_{1/2} = \frac{0.693}{\lambda} = \frac{0.693}{0.0693\text{ day}^{-1}} = 10\text{ days}$.

PYQ Patterns

These are pattern-based practice questions. Authentic year labels are only used when verified from a source.

1. The half-life of a radioactive substance is $20\text{ minutes}$. The time taken between $50%$ decay and $87.5%$ decay of the substance is:

Explanation: $50%$ decay leaves $50%$ remaining ($1$ half-life). $87.5%$ decay leaves $12.5%$ remaining ($3$ half-lives, since $(1/2)^3 = 1/8 = 12.5%$). The time elapsed between $1$ half-life and $3$ half-lives is $3T_{1/2} - 1T_{1/2} = 2T_{1/2} = 2 \times 20 = 40\text{ minutes}$. Wait, let's re-verify: from $50%$ decayed (remaining $50%$) to $87.5%$ decayed (remaining $12.5%$). Remaining goes from $N_0/2$ to $N_0/8$, which is a drop of two half-lives ($2 \times 20 = 40$ minutes). Let's check options: 40 minutes is option D. Correct index should be 3.

2. A radioactive sample has an initial activity of $64\text{ Bq}$. If its half-life is $2\text{ hours}$, what will its activity be after $6\text{ hours}$?

Explanation: Number of half-lives $n = \frac{t}{T_{1/2}} = \frac{6\text{ hours}}{2\text{ hours}} = 3$. Activity $A = A_0 \left(\frac{1}{2}\right)^3 = 64 \times \frac{1}{8} = 8\text{ Bq}$.

3. Two radioactive materials $X$ and $Y$ have decay constants $\lambda_x = 3lambda$ and $\lambda_y = \lambda$. If they start with the same number of nuclei, the ratio of the number of undecayed nuclei of $X$ to that of $Y$ after time $t = \frac{1}{2lambda}$ is:

Explanation: $N_x = N_0 e^{-3lambda t}$, $N_y = N_0 e^{-\lambda t}$. $\frac{N_x}{N_y} = e^{-2lambda t}$. For $t = \frac{1}{2lambda}$, $\frac{N_x}{N_y} = e^{-2lambda \left(\frac{1}{2lambda}\right)} = e^{-1}$.

4. The activity of a radioactive preparation fallsing from $10,000\text{ s}^{-1}$ to $1250\text{ s}^{-1}$ in $30\text{ days}$. The half-life of the substance is:

Explanation: Ratio of activity $\frac{A}{A_0} = \frac{1250}{10000} = \frac{1}{8} = \left(\frac{1}{2}\right)^3$. Thus, $3$ half-lives elapsed in $30\text{ days}$, so $T_{1/2} = \frac{30}{3} = 10\text{ days}$.

5. In a radioactive decay chain, the parent nuclide has a decay constant $\lambda_1$ and the daughter has $\lambda_2$. If secular equilibrium is established, the ratio of the number of daughter nuclei $N_2$ to parent nuclei $N_1$ is given by:

Explanation: At secular equilibrium, $\lambda_1 N_1 = \lambda_2 N_2$, which rearranges to $\frac{N_2}{N_1} = \frac{\lambda_1}{\lambda_2}$.

6. The mean life $\tau$ of a radioactive sample is $1440\text{ years}$. Its half-life is approximately:

Explanation: $T_{1/2} = 0.693 \times \tau = 0.693 \times 1440\text{ years} \approx 997.92\text{ years} \approx 998\text{ years}$.

Timed Topic Test

Attempt these questions under a ten-minute limit using a separate timer.

1. If $10%$ of a radioactive substance decays in $5\text{ days}$, what percentage of the original amount will remain undecayed after $20\text{ days}$?

Explanation: Fraction remaining after $t$ days is given by $N/N_0 = e^{-\lambda t}$. Given $e^{-5lambda} = 0.90$. After $20\text{ days}$ ($4$ intervals of $5\text{ days}$), remaining fraction is $(e^{-5lambda})^4 = (0.90)^4 = 0.6561$, which is $65.6%.$

2. Which of the following particles is emitted during $\beta$-plus ($\beta^+$) decay?

Explanation: In $\beta^+$ decay, a proton converts into a neutron, a positron (positive electron), and an electron neutrino.

3. The disintegration constant of a radioactive element is $0.005\text{ day}^{-1}$. Calculate its half-life ($\ln 2 \approx 0.693$):

Explanation: $T_{1/2} = \frac{0.693}{0.005} = 138.6\text{ days}$.

4. What is the probability of a radioactive nucleus decaying within a time interval equal to its mean life $\tau$?

Explanation: The fraction decayed up to time $t = \tau$ is $1 - \frac{N(\tau)}{N_0} = 1 - e^{-\lambda (1/\lambda)} = 1 - e^{-1} \approx 0.632$ or $63.2%.$

5. If two radioactive substances $A$ and $B$ have half-lives $T_A$ and $T_B$ respectively, and initially have equal numbers of nuclei, what is the ratio of their decay rates after a long time?

Explanation: Activity is given by $\lambda N$. Since $\lambda = \frac{0.693}{T_{1/2}}$, the decay rates depend on their respective decay constants and remaining numbers of nuclei.

6. $\gamma$ emission from an excited nucleus results in changes to:

Explanation: $\gamma$ rays are photons emitted during transitions between nuclear energy states; hence, neither $Z$ nor $A$ changes.

7. The activity of a radioactive sample drops to $\frac{1}{32}$ of its initial value in $25\text{ hours}$. The half-life of the sample is:

Explanation: $\frac{1}{32} = \left(\frac{1}{2}\right)^5$, so $5$ half-lives equal $25\text{ hours}$. Thus, $T_{1/2} = \frac{25}{5} = 5\text{ hours}$.

8. In a nuclear decay, if the parent nucleus emits an $\alpha$ particle, the mass number $A$ and atomic number $Z$ change by:

Explanation: An $\alpha$ particle is $^{4}_{2}\text{He}$, so emission decreases the mass number by $4$ and the atomic number by $2$.

9. The decay constant of a radioactive substance is $0.1\text{ s}^{-1}$. What is the time during which the number of undecayed nuclei reduces to $1/e$ of its initial value?

Explanation: The time required for nuclei to reduce to $1/e$ of initial value is the mean life $\tau = \frac{1}{\lambda} = \frac{1}{0.1} = 10\text{ s}$.

10. Which among the following hypotheses was introduced to account for the continuous energy spectrum of $\beta$ particles?

Explanation: Wolfgang Pauli proposed the neutrino (antineutrino) hypothesis to explain the continuous energy distribution and conservation of energy/momentum in $\beta$ decay.